The properties and uses of arsenic sulfide As2S3

 Overview of arsenic sulfide As2S2

Arsenic sulfide is an inorganic compound with the chemical formula As2S3, also known as arsenic sulfide. This ore is called orpiment, a common realgar (arsenic disulfide) mineral, and a common "miner". Pure arsenic trisulfide is lemon yellow and belongs to the monoclinic crystal system. It is composed of (As2S3)N layered crystal lattice. It melts into a red liquid at 300°C and does not decompose when it boils at 707°C. Arsenic trisulfide is insoluble in water and mineral acids, but soluble in sodium sulfide, alkali metal hydroxides and carbonates. poisonous. Na3ASS3 is called sodium thioarsenite, and it can also exist in the form of impregnated NaASS2. Sulfurarsenic acid is unstable and easily decomposes.

Arsenic trisulfide is a semiconductor with a direct band gap of 2.7 eV. Its wide band gap makes it transparent to infrared light between 620 nm and 11 μm.

Realgar belongs to the monoclinic crystal system, and the crystal group is P2(1)/n. The crystals are orange-red, transparent to translucent realgar crystals. The columnar crystals are of varying lengths, accompanied by thick and thin, and grow in multiple directions. The crystal is diamond luster, and the fracture is resin luster. Single crystals are small columnar and needle-shaped, but natural single crystals are relatively rare.

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As2S3 exists in two forms: crystalline and amorphous. Both forms have a polymer structure composed of triangular pyramid As(III) centers connected by sulfide centers. The sulfide center has dual coordination with two arsenic atoms. In the crystalline form, the compound has a corrugated plate structure. The bond between the sheets is composed of van der Waals forces. Crystalline forms are usually found in geological samples. Amorphous As2S3 has no layered structure, but has a high degree of crosslinking.

Application of arsenic sulfide As2S2

Arsenic minerals are mainly used to extract elemental arsenic and produce arsenic acid and arsenic compounds, such as calcium arsenate, sodium arsenate, lead arsenate and so on. In the metallurgical industry, it is used to make arsenic alloys; arsenic-lead alloys are used in the military industry to make bullets, military poisons and fireworks; arsenic-copper alloys are used to make radar parts and automobiles; in light industry, they are used to make milky white glass, Glass decolorization, wool soaking, tanning agents and wood preservation; used in agriculture as pesticides, herbicides, rodenticides and other arsenic pesticides; arsenic products are called arsenic. Realgar concentrate powder can be used to make firecrackers and fireworks.

Arsenic trisulfide can be used as a pigment, reducing agent and medicine.

As the refractive index of As2S3 is 2.45 higher than the refractive index of organic photoresist, and the Knoop hardness is higher, it is researched to manufacture photonic crystals with complete photonic band gap. Research the advancement of laser plate making technology, such as 3D direct laser engraving (3D DLW) and chemical wet etching, so that AS2S3 can be used as a photoresist to prepare 3D nanostructures

AS2S3 and AS4S4 are used as treatment methods for acute promyelocytic leukemia (APL).

Amorphous arsenic trisulfide is used as chalcogenide glass in infrared optical devices. It is transparent between 620 nm and 11 μm.

Arsenic trisulfide glass is more resistant to oxidation than crystalline arsenic trisulfide, thereby minimizing toxicity.

Arsenic Sulfide As2S2 Price

The price of arsenic sulfide As2S2 will vary randomly with factors such as arsenic sulfide As2S2 production costs, transportation costs, international conditions, exchange rates, and arsenic sulfide market supply and demand conditions. Tanki New Materials Co., Ltd. aims to help various industries and chemical wholesalers find high-quality, low-cost nanomaterials and chemicals by providing a full set of customized services. If you are looking for arsenic sulfide As2S2, please feel free to send an inquiry to get the latest price of arsenic sulfide As2S2.

Arsenic Sulfide As2S2 Supplier

As a global arsenic sulfide As2S2 supplier, Tanki New Materials Co., Ltd. has extensive experience in the performance, application and cost-effective manufacturing of advanced engineering materials. The company has successfully developed a series of powder materials (molybdenum disulfide, nickel disulfide), kun disulfide), high-purity targets, functional ceramics and structural devices, and provides OEM services.

Arsenic Sulfide As2S3 Powder Properties
Other NamesArsenic(3+) trisulfide, arsenic sulphide, arsenic; sulfane,
diarsenic trisulfide, arsenic(3+) trihydride trisulfide, arsenic trisulfide,
Orpiment, CAS 12612-21-4, EC 235-720-6
CAS No.1303-32-8
Compound FormulaAs2S3
Molecular Weight246.0382
AppearanceBright yellow to orange crystals or powder
Melting Point310 °C, 583 K, 590 °F
Solubility in waterN/A
Density3.43 g/cm3
Purity99.90%
Particle Size-100mesh
Boling point707 °C, 980 K, 1305 °F
Specific HeatN/A
Thermal ConductivityN/A
Thermal ExpansionN/A
Young's ModulusN/A
Exact Mass245.7594 g/mol
Monoisotopic Mass 245.7594 g/mol
Arsenic Sulfide As2S3 Powder Health & Safety Information
Safety WarningDanger
Hazard StatementsH301 + H311 + H331-H410
Flashing pointN/A
Hazard CodesT,N
Risk Codes23/25-50/53
Safety Statements20/21-28-45-60-61
RTECS NumberCG2638000
Transport InformationUN 1557 6.1/PG II
WGK Germany3


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